Question Video: Naming the Two Processes Which Establish a Constant Vapor Pressure When in Equilibrium | Nagwa Question Video: Naming the Two Processes Which Establish a Constant Vapor Pressure When in Equilibrium | Nagwa

Question Video: Naming the Two Processes Which Establish a Constant Vapor Pressure When in Equilibrium Chemistry • First Year of Secondary School

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In a closed system, a constant vapor pressure results from the formation of a dynamic equilibrium between the vapor and the liquid. At this equilibrium, which two opposing processes are occurring at the same rate?

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Video Transcript

In a closed system, a constant vapor pressure results from the formation of a dynamic equilibrium between the vapor and the liquid. At this equilibrium, which two opposing processes are occurring at the same rate?

The vapor pressure is the pressure exerted by a vapor above its liquid when the vapor and the liquid are in equilibrium with each other. The equilibrium that is reached inside this beaker is a dynamic equilibrium. In a dynamic equilibrium, two processes are occurring at the same rate, so no macroscopic change is observed. If we could look inside our beaker at the atomic level, we’d see that the molecules inside are constantly moving. In fact, sometimes we would see molecules in the liquid phase gain enough energy to become a vapor, which describes the process of evaporation. At the same time, we would also see the molecules in the vapor phase join the liquid phase if they lose enough energy. In other words, those molecules are condensing.

Because the processes of evaporation and condensation are occurring at the same rate, there is a dynamic equilibrium between the vapor and the liquid, which results in a constant vapor pressure. So the two opposing processes that are occurring at the same rate are the evaporation of the liquid and the condensation of the vapor.

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