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Question Video: Assigning a pH for a Common Material Chemistry • First Year of Secondary School

Calcium carbonate will produce a fizz of carbon dioxide when added to lemon juice. Based on this observation, what can be said about the pH of lemon juice?

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Video Transcript

Calcium carbonate will produce a fizz of carbon dioxide when added to lemon juice. Based on this observation, what can be said about the pH of lemon juice?

Calcium carbonate is an example of a metal carbonate, and the question tells us that mixing calcium carbonate and lemon juice produces carbon dioxide. This might remind you of the classic reaction of a metal carbonate with an acid, which produces a metal salt, carbon dioxide, and water. There are no observations related to the production of the metal salts or the water because they stay in the liquid. But we do see bubbles of carbon dioxide gas. So the question is pointing us towards the conclusion that lemon juice is acidic.

pH is the measure of acidity of a solution. Pure water at 25 degrees Celsius has a pH of seven and is considered neutral. A solution with a pH of zero is very acidic. And a solution with pH 14 is very basic. In order to react with a carbonate, lemon juice must have a pH less than seven and therefore be acidic. Therefore, since lemon juice does react with calcium carbonate as confirmed by the production of carbon dioxide, we know that the pH of lemon juice must be less than seven. With only this observation, this is as precise as we can be.

In practice, we’d expect the pH of lemon juice to be meaningfully below seven because producing carbon dioxide at a visible rate will require a relatively high acidity. For now, less than seven is the best that we can do.

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