# Worksheet: Hess Cycles Using Bond Energies

In this worksheet, we will practice calculating reaction enthalpies by comparing the standard bond enthalpies of the reactants and the products.

Q1:

What is the approximate enthalpy change for the reaction shown?

Use the bond enthalpies from the table.

 Bond Bond Enthalpy (kJ/mol) BrBr HBr HH 190 370 436

Q2:

What is the approximate enthalpy change for the reaction shown? Use the bond enthalpies from the table.

 Bond Bond Enthalpy (kJ/mol) CH CC CO HO OO 415 611 741 464 498

Q3:

What is the approximate enthalpy change for the reaction shown? Use the bond enthalpies from the table.

 Bond Bond Enthalpy (kJ/mol) CH CI HI II 415 240 295 150

Q4:

When a molecule can form two different structures, the structure with the stronger bonds is usually the more stable form. Using the bond energy values listed in the table, identify the correct structure of the hydroxylamine molecule.

 Bond Bond Enthalpy (kJ/mol) HN HO NO 390 464 200
• A
• B

Q5:

Given that the energy of a bond is 104 kcal/mol and that of an bond is 119 kcal/mol, what is the reaction enthalpy for the following reaction?

Q6:

The energies of selected bonds are shown in the table.

 Bond Bond Energy (kcal/mol) CH CCl HCl ClCl 104 85 103 58

The chlorination of methane is described by the equation shown. Using the values in the table, calculate the energy change in this reaction per mole of methane reacted.

Q7:

Hydrogen fluoride gas is formed by the reaction of hydrogen with fluorine, as shown.

The standard enthalpy change for this reaction is kJ/mol. The molar bond energies of and are 436 kJ/mol and 159 kJ/mol respectively. Calculate the energy of one bond.

• A J
• B J
• C J
• D J
• E J

Q8:

Gaseous sulfuric acid decomposes at high temperature to form sulfur dioxide, oxygen, and steam. The bonds in these molecules have different energies, as indicated in the diagram. All labeled bond energies are in units of kilojoules per mole. Calculate the enthalpy change for this reaction per mole of oxygen gas produced.