Worksheet: Rate Laws from Initial Rates
In this worksheet, we will practice using measurements of initial rate to deduce the rate law of a reaction and the order of reaction for each reactant.
Q1:
In a reaction between compounds and , doubling the concentration of increases the rate of reaction by a factor of 4. However, tripling the concentration of reactant increases the rate by a factor of 3.
What is the order of reaction with respect to ?
What is the order of reaction with respect to ?
Q3:
Hypochlorite and iodide ions react to form hypoiodite and chloride ions: The initial rate of reaction was measured at three different reactant concentrations, as shown in the table.
| (M) | (M) | Initial Rate (M/s) |
|---|---|---|
Determine the rate law for this reaction.
- ARate =
- BRate =
- CRate =
- DRate =
- ERate =
Determine the appropriate units for the rate constant of this reaction, .
- AL3/mol3⋅s
- Bs−1
- CM/s
- DL/mol⋅s
- EL2/mol2⋅s
Expressing concentrations in molars and time in seconds, estimate, to 3 significant figures, the numerical value of the rate constant, .
- A
- B
- C
- D
- E
Q4:
Nitric oxide reacts with chlorine to form nitrosyl chloride : The initial rate of reaction of nitric oxide was measured at three different reactant concentrations, as shown in the table.
| (M) | (M) | Initial Rate (M/s) |
|---|---|---|
| 0.100 | 0.100 | |
| 0.100 | 0.150 | |
| 0.150 | 0.100 |
Determine the rate law for this reaction.
- ARate =
- BRate =
- CRate =
- DRate =
- ERate =
Determine the appropriate unit for the rate constant of this reaction, .
- AL/mol⋅s
- BL3/mol3⋅s
- Cs−1
- DL2/mol2⋅s
- EM/s
Expressing concentrations in units of molars and times in units of seconds, estimate, to 3 significant figures, the numerical value of the rate constant, .
Q5:
| Time (s) | 4.00 | 8.00 | 12.0 | 16.0 | 20.0 |
|---|---|---|---|---|---|
| (M) | 0.220 | 0.144 | 0.110 | 0.088 | 0.074 |
By plotting suitable functions of the tabulated data, determine the appropriate unit for the rate constant of this reaction.
- AL/mol⋅s
- BL3/mol3⋅s
- Cs−1
- DM/s
- EL2/mol2⋅s
Expressing concentrations in molars and time in seconds, estimate, to 3 significant figures, the numerical value of the rate constant for this reaction.