Lesson Worksheet: Reactions of Alcohols Chemistry

In this worksheet, we will practice describing various reactions of alcohols and predicting what products are formed.

Q1:

Excess ethanol was reacted with concentrated sulfuric acid at 130C to produce a product with the molecular formula CHO410. The product was found not to be an alkene or an alcohol. What class of molecule might the product be?

  • AEther
  • BKetone
  • CEster
  • DAlkane
  • EAnhydride

Q2:

A piece of sodium metal was dropped into a sample of methanol.

What organic product, if any, is formed from this reaction?

  • ASodium methyl
  • BMethanoic acid
  • CSodium methanoate
  • DMethanal
  • ESodium methoxide

What gas does this reaction produce?

  • AWater vapor
  • BHydrogen
  • CCarbon dioxide
  • DOxygen
  • EMethane

Q3:

Which of the following is true upon the reaction of ethanol with sodium metal?

  • AFormation of sodium ethoxide with the evolution of hydrogen gas
  • BFormation of sodium ethoxide with the evolution of carbon dioxide gas
  • CFormation of sodium acetate with the evolution of hydrogen gas
  • DFormation of sodium acetate with the evolution of carbon dioxide gas
  • EFormation of sodium ethoxide with the evolution of carbon monoxide gas

Q4:

The reaction scheme below shows various reactions a molecule of propan-2-ol can undergo:

Which product would be a ketone?

  • AA
  • BB
  • CC

What name would product C have?

  • A2-Chloropropan-2-ol
  • B2-Chloropropane
  • C1-Chloropropane

How many different positional isomers would result from the reaction to form product A?

  • A1 isomer
  • B2 isomers
  • C4 isomers
  • D3 isomers

Q5:

Consider the following reaction:

+HClZnCl2CCH2CH2CH2CH2CH2OHCH3

What product is formed from this reaction?

  • A
    CCH2ClCH2ClCH2CH2CH2
  • B
    CCH2CHCH2CH2CH2Cl
  • C
    CCH3CH2ClCH2CH2CH2CH2
  • D
    CCH2CHOHCH2CH2CH2
  • E
    CCH2OHCH2ClCH2CH2CH2CH2

Q6:

Two different experiments were performed under different reaction conditions with propan-1-ol. Details on each experiment are shown in the scheme below.

What are the names of products A and B?

  • AA: propanone, B: propanal
  • BA: propanal, B: propanone
  • CA: propanone, B: propanoic acid
  • DA: propanoic acid, B: propanal
  • EA: propanal, B: propanoic acid

Q7:

Fill in the blanks: Complete oxidation of ethanol using acidified potassium dichromate solution produces that has a odor.

  • Aacetaldehyde, fruity
  • Bethanoic acid, vinegary
  • Cacetone, fruity
  • Dmethanoic acid, pungent
  • Eethanoic acid, fruity

Q8:

Acetic acid reacts with ethanol, forming ethyl acetate.

What catalyst could be used in this reaction?

  • ACuSO4
  • BHgSO4
  • CHSO24
  • DKMnO4
  • EKCrO24

Which of the following is the other name of the ester produced?

  • AEthyl ethanoate
  • BEthyl methanoate
  • CMethyl formate
  • DMethyl propanoate
  • EMethyl ethanoate

Q9:

The following product results from the oxidation of an alcohol:

CH3CH2CH2CCH3O

Was the alcohol primary, secondary, or tertiary?

  • ATertiary
  • BPrimary
  • CSecondary

Which of the following alcohols could the reactant be?

  • A
    CH3CH2CH2CH2CH2OH
  • B
    CH3COHCH2CH3CH3
  • C
    CH3CH2CHOHCH2CH3
  • D
    CH3CH2CH2CHOHCH3

Q10:

The reaction scheme for the oxidation of 1-propanol is as follows:

[O]H2CH3CH2COHCH3CH2CHO

What does the symbol [O] represent in this reaction?

  • AOxygen from an oxidizing agent
  • BThe loss of an oxygen
  • COxygen from the air
  • DOxygen from the alcohol
  • EThe addition of an oxygen

What general class of molecules does the product belong to?

  • AEsters
  • BAldehyde
  • CCarboxylic acid
  • DKetone
  • EAmides

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