Question Video: Discerning the More Effective Catalyst for Hydrogen Peroxide Decomposition | Nagwa Question Video: Discerning the More Effective Catalyst for Hydrogen Peroxide Decomposition | Nagwa

Question Video: Discerning the More Effective Catalyst for Hydrogen Peroxide Decomposition Chemistry • Third Year of Secondary School

Copper(II) oxide and chromium(III) oxide can both be used as catalysts for the decomposition of hydrogen peroxide, as shown: 2H₂O₂ (aq) ⟶ 2H₂O (l) + O₂ (g) In experiment A, copper(II) oxide is used, and in experiment B, chromium(III) oxide is used. The results are shown on the graph below. Which of the catalysts is the best and why?

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Video Transcript

Copper(II) oxide and chromium(III) oxide can both be used as catalysts for the decomposition of hydrogen peroxide, as shown: two H2O2 aqueous reacts to form two H2O liquid plus O2 gas. In experiment A, copper(II) oxide is used, and in experiment B, chromium(III) oxide is used. The results are shown on the graph below. Which of the catalysts is the best and why? (A) Chromium(III) oxide is the better catalyst; the less steep slope indicates a faster rate of reaction. (B) Chromium(III) oxide is the better catalyst; the steeper slope indicates a faster rate of reaction. (C) Copper(II) oxide is the better catalyst; the less steep slope indicates a faster rate of reaction. Or (D) copper(II) oxide is the better catalyst; the steeper slope indicates a faster rate of reaction.

In this question, we’re looking to identify the most effective catalyst. We also need to explain our choice.

The figure shows the decomposition of hydrogen peroxide in the presence of two different substances. The red and blue lines represent copper(II) oxide and chromium(III) oxide, respectively. You’ll notice that both lines have a similar shape, but one has a steeper slope than the other. The graphs have the mass of the reaction vessel on the 𝑦-axis and time on the 𝑥-axis.

We can infer that a steeper line represents a more rapid decomposition of hydrogen peroxide reactant. This is because the loss of mass is what indicates hydrogen peroxide decomposition, where the product, oxygen, is lost as a gas into the atmosphere, decreasing the mass of the vessel. In the chart shown, the blue line has a steeper slope and therefore represents hydrogen peroxide turning into water and oxygen more rapidly.

And with this information, we can answer the question. Which catalyst, copper(II) oxide or chromium(III) oxide, is the best catalyst for the decomposition of hydrogen peroxide? And because the steeper slope correlates to a better catalyst, we can choose answer choice (B) as the correct answer. Chromium(III) oxide is the better catalyst; the steeper slope indicates a faster rate of reaction.

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