Video Transcript
In this video, we will learn how to
describe and identify energy levels in atoms and determine the number of electrons
each energy level can contain.
Atoms are the smallest unit of
ordinary matter that forms a chemical element. They are composed of subatomic
particles. There are three types of subatomic
particles: positively charged protons, neutral neutrons, and negatively charged
electrons. Despite containing both positively
and negatively charged particles, atoms are neutral overall. This is because an atom contains
the same number of positively charged protons and negatively charged electrons. The positively charged protons and
neutral neutrons are found in the nucleus in the center of the atom. The negatively charged electrons
stay in a different part of the atom called energy levels. But what exactly are energy
levels?
Energy levels, sometimes called
electron shells, are regions around the nucleus in which electrons move according to
their energies. The seven lowest energy levels in
an atom are represented by the blue arcs in this diagram. Each has a different energy. The energy level closest to the
nucleus has the lowest energy. The energy increases the farther
away the energy level is from the nucleus.
Each energy level can be identified
by a number or a single capital letter. The energy level closest to the
nucleus is K, followed by L, M, N, and so on. Not only do the energy levels have
a different energy, but each also has a different maximum number of electrons that
it can contain. The K energy level can only contain
a maximum of two electrons. But the N energy level can contain
a maximum of 32 electrons.
We can determine how many electrons
an energy level can hold by using the equation two 𝑛 squared. In this equation, 𝑛 indicates the
energy level, with K being energy level one, L being two, and so on. Using this equation, we can
determine the maximum number of electrons that the L energy level can contain. First, we substitute two for
𝑛. Two squared is four, and two times
four is eight. Therefore, the L energy level can
hold a maximum of eight electrons. What about the M energy level? This is energy level three. Three squared is nine, and two
times nine is 18. So the M energy level can hold a
maximum of 18 electrons.
We can see that the maximum number
of electrons that an energy level can hold dramatically changes from one energy
level to the next. We might say that the number of
electrons an energy level can hold increases exponentially. The equation two 𝑛 squared can be
used to determine the maximum number of electrons in the K through N energy
levels. But we don’t typically apply this
equation to energy levels O and beyond. This is because atoms tend to split
into two when an energy level contains more than 32 electrons. We now know what energy levels are
and how many electrons each can hold. But which energy levels do
electrons in an atom occupy?
It turns out that electrons in an
atom tend to fill the lowest possible energy levels before filling higher ones. This means that all of the
electrons in an atom will ordinarily have the lowest possible energy state. To see this in practice, let’s take
a look at an atom of helium, lithium, and magnesium.
An atom of helium has two
protons. Therefore, it must also have two
electrons. The electrons will fill or occupy
the lowest possible energy level. The lowest energy level is the K
energy level, which can hold two electrons. So both of the helium electrons,
each represented by a blue dot, will be found in the K energy level.
An atom of lithium has three
protons and therefore three electrons, one more electron than an atom of helium. We know that electrons will occupy
the lowest possible energy level first. But the K energy level can only
hold two electrons, and a lithium atom has three. So the first two electrons will
fill the K energy level, and the third electron will occupy the next highest energy
level, which is the L energy level.
An atom of magnesium has 12 protons
and 12 electrons. The first two electrons fill the K
energy level. The L energy level can only hold
eight electrons. So the next eight electrons will
fill the L energy level. So far, the diagram only shows 10
electrons. The remaining two electrons must be
in the next highest energy level, which is the M energy level.
All three of these atoms are in
what we call the ground state. The ground state is the lowest
possible energy state of an atom. It is achieved when all of the
electrons are in the lowest possible energy levels. Electrons tend to stay in the
lowest possible energy levels. So atoms are typically in the
ground state. However, it is possible for an
electron to move to a higher energy state.
Let’s consider a hydrogen atom that
has one proton and one electron. In the ground state, its single
electron will be found in the lowest energy level, K. Electrons like this one can move to
a higher energy level if they absorb a quantum with the right energy. A quantum is a unit or packet of
energy. The amount of energy that an
electron needs in order to move depends on the energy of the energy level it starts
at and the energy of the energy level it moves to. The amount of energy an electron
needs in order to move between two energy levels can be calculated by subtracting
the energy of the level that the electron currently occupies from the energy of the
level that the electron will move to.
Let’s determine how much energy
this electron will need in order to move to the M energy level. The energy of the M energy level is
negative 1.5 energy units. The energy of the K energy level
that the electron is currently in is negative 13.6 energy units. By subtracting negative 13.6 energy
units from negative 1.5 energy units, we can determine how much energy the electron
needs in order to move from the K energy level to the M energy level. This gives us a value of 12.1
energy units. So, if an electron in the K energy
level absorbs a quantum with 12.1 energy units, it can move to the M energy
level.
Because the electron has moved to a
higher energy level, this atom is no longer in the ground state but is in what we
call an excited state. The electrons in an excited-state
atom are not in the lowest possible energy states. Excited-state atoms tend to be
unstable and do not stay excited for very long. The excited electron will quickly
move back to the ground state.
In order for the electron to move
back to the ground state, energy must be emitted or released. The amount of energy released is
the same as the amount of energy the electron absorbed. In this example, the electron
absorbed a quantum with 12.1 energy units and then transitioned from the K energy
level to the M energy level. So, in order for this electron to
move from the M energy level back to the K energy level, it must emit 12.1 energy
units.
We’ve learned a lot about electrons
and energy levels in this video. But before we summarize what we’ve
learned, let’s take a look at a few questions.
What is the maximum number of
electrons that can occupy energy level X shown in the diagram?
Energy levels are regions around
the nucleus in which electrons move according to their energies. The energy levels each have a
different energy. The energy level closest to the
nucleus has the lowest energy. And the energy increases as the
energy levels get farther from the nucleus.
In addition to having a different
energy, each energy level can hold a different maximum number of electrons. For energy levels one through four,
we can calculate the maximum number of electrons each can contain using the equation
two 𝑛 squared. 𝑛 in this equation represents the
energy level.
To answer the question, we need to
determine the maximum number of electrons that the energy level marked X can
contain. The X energy level is energy level
number three. So we can substitute three for 𝑛
in the equation. Three squared is nine, and two
times nine is 18. So the maximum number of electrons
that can occupy energy level X in the diagram is 18 electrons.
Which of the diagrams shows the
ground state for an atom that contains two electrons?
Electrons in an atom occupy energy
levels. Energy levels are regions around
the nucleus in which electrons move according to their energies. The energy level closest to the
nucleus in an atom is the K energy level. The second energy level is the L
energy level. The third energy level is the M
energy level. And the fourth is the N energy
level. With this information, we can
eliminate answer choices (D) and (E) as the energy levels are not labeled
correctly. Let’s remove these answer choices
from the screen to finish discussing the question.
We are told that the atom in the
question is in the ground state. The ground state is the lowest
possible energy state of an atom. The ground state is achieved when
all of the electrons in an atom are in the lowest possible energy levels. Of the four energy levels shown,
the energy level with the lowest energy is energy level K. The energy levels increase in
energy the farther they are from the nucleus. So we should expect that for an
atom to be in the ground state, the electrons should fill the K energy level first,
followed by L then M then N.
We now know the order in which the
electrons will fill the energy levels. But we need to know how many
electrons each energy level can hold. The K energy level can contain a
maximum of two electrons. The L energy level can hold up to
eight, M up to 18, and N up to 32. The atom in the question, which is
in the ground state, contains two electrons. The first electron will occupy the
lowest energy level, level K. The second electron will also be
found in the K energy level, as this energy level can hold up to two electrons. So an atom that contains two
electrons will be in the ground state when both of those electrons occupy the K
energy level. This is represented by the diagram
shown in answer choice (C).
Now let’s summarize what we’ve
learned with the key points. Atoms are electrically neutral
because they contain the same number of positively charged protons and negatively
charged electrons. Electrons occupy and move in
regions outside of the nucleus, called energy levels, that are labeled K through
Q. The energy of the energy levels
increases the farther the energy level is from the nucleus. The maximum number of electrons an
energy level can hold can be calculated using the equation two 𝑛 squared.
Electrons in an atom fill the
lowest possible energy levels first before filling higher ones. The ground state is the lowest
possible energy state of an atom, where all of the electrons are in the lowest
possible energy levels. Electrons can move to a higher
energy level if they absorb a quantum with the right amount of energy. Atoms are in the excited state when
electrons are not in the lowest possible energy states.