Question Video: Explaining Why the Erlenmeyer Flask Must Be Swirled during a Titration | Nagwa Question Video: Explaining Why the Erlenmeyer Flask Must Be Swirled during a Titration | Nagwa

Question Video: Explaining Why the Erlenmeyer Flask Must Be Swirled during a Titration Chemistry • Third Year of Secondary School

When adding a solution from a buret into an Erlenmeyer flask, why is it important that the flask is swirled?

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Video Transcript

When adding a solution from a buret into an Erlenmeyer flask, why is it important that the flask is swirled?

The experiment described in the question is a titration experiment. In a titration experiment, a solution with a known concentration is added to an exact volume of a solution with an unknown concentration in the presence of an indicator. The solution with the known concentration is called the titrant, and the solution with the unknown concentration is called the titrand or analyte.

The apparatus shown could be used to carry out an acid–base titration. Let’s say the buret contains a basic solution with a known concentration. Then, the Erlenmeyer flask would contain a specific volume of acid and phenolphthalein indicator. In an acidic solution, phenolphthalein indicator is colorless. At a pH of about 8.2, phenolphthalein turns faint pink. As a solution becomes even more basic, phenolphthalein turns darker pink.

As we slowly add the base to the acidic solution in the Erlenmeyer flask, we should continuously swirl the solution in the flask. As we continue to add the base and swirl the solution, we will notice that the solution begins to turn pink. However, when we swirl the solution, the pink color goes away and the solution turns colorless again. This is because all of the base that was added quickly reacted with the acid and the pH of the solution is still below seven. But soon after adding more base, the swirling does not make it go away and the faint pink color persists.

At this point, we have added just enough base to neutralize all of the acid in the flask. This point is called the equivalence point, and we should stop our experiment and read the buret to determine how much base was added. If we continued to add more base, the solution would turn darker pink as the pH rises. This is because there is no more acid in the flask to react with the base that has been added. To get the most accurate measurement of how much base is needed to react with the acid, we need to ensure the solutions are continuously mixed together well so that they can fully react.

In conclusion, when adding a solution from a buret into an Erlenmeyer flask, it is important that the flask is swirled to ensure the solutions are mixed.

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