Question Video: Classifying Ammonia and Boron Trifluoride during the Formation of Ammonia Boron Trifluoride Using the Lewis Definition of Acids and Bases Chemistry

Ammonia boron trifluoride molecules are formed when an ammonia molecule donates a bonding pair of electrons to a boron trifluoride molecule. The structure of the ammonia boron trifluoride molecule is shown below. Which of the following statements correctly describes the ammonia and boron trifluoride molecules during the formation of the ammonia boron trifluoride molecule? [A] The boron trifluoride and ammonia molecules both act as a Lewis acid. [B] The boron trifluoride and ammonia molecules both act as a Lewis base. [C] The boron trifluoride molecule acts as a Lewis base and the ammonia molecule acts as a Lewis acid. [D] The ammonia molecule acts as a Lewis base and the boron trifluoride molecule acts as a Lewis acid.

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Video Transcript

Ammonia boron trifluoride molecules are formed when an ammonia molecule donates a bonding pair of electrons to a boron trifluoride molecule. The structure of the ammonia boron trifluoride molecule is shown below. Which of the following statements correctly describes the ammonia and boron trifluoride molecules during the formation of the ammonia boron trifluoride molecule? (A) The boron trifluoride and ammonia molecules both act as a Lewis acid. (B) The boron trifluoride and ammonia molecules both act as a Lewis base. (C) The boron trifluoride molecule acts as a Lewis base and the ammonia molecule acts as a Lewis acid. Or (D) the ammonia molecule acts as a Lewis base and the boron trifluoride molecule acts as a Lewis acid.

Ammonia boron trifluoride is an example of a compound where a coordinate bond is formed between two molecules: ammonia and boron trifluoride. A coordinate covalent bond is a covalent bond where the pair of electrons forming the bond is donated from one atom only. In the case of ammonia boron trifluoride, the donor atom is the nitrogen atom of ammonia and the acceptor atom is the boron atom of boron trifluoride. The prerequisite to becoming a donor atom in this type of bonding is to have a surplus of electrons that can be donated. The acceptor atom, on the other hand, has a scarcity of electrons and so receives them. Nitrogen is the donor atom as it has a lone pair of electrons, which makes it electron rich. Boron is the acceptor atom as it has an empty p orbital, which can receive a pair of electrons.

In this molecule, the nitrogen of ammonia donates both the bonding electrons to the boron of boron trifluoride, forming a coordinate bond, which leads to the formation of ammonia boron trifluoride. As ammonia donates a pair of electrons, we can call it a Lewis base. This is because a Lewis base is defined as a substance that can donate a lone pair of electrons, forming a bond. This makes boron trifluoride a Lewis acid. A Lewis acid is a substance that can accept a lone pair of electrons, forming a bond.

Let’s bring back the answer choices. We now know that the correct answer is (D). The ammonia molecule acts as a Lewis base and the boron trifluoride molecule acts as a Lewis acid.

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