Video Transcript
In this video, we will learn what a
chemical salt is, look at how they are named, and describe the preparation of
soluble and insoluble salts. We will also examine why we
consider certain salts acidic, neutral, or basic.
A salt is a type of chemical
compound. The International Union of Pure and
Applied Chemistry, IUPAC, considers any chemical consisting of an assembly of
cations and anions to be a salt. Cations are positively charged ions
and anions are negatively charged ions. So for some people, any ionic
compound is a salt, and all salts are ionic compounds.
Practically speaking, when we refer
to salts, we often refer to those specific ionic compounds that can be produced by
the reaction of an acid and a base. In this case, we’re only
considering the type of acid with H+ ions that can be donated. These are Brønsted-Lowry acids. You may see this reaction, an acid
plus a base reacts to form salt plus water. This equation only really applies
when we’re dealing with a base with OH− ions. This is otherwise known as an
alkali or an Arrhenius base. However, a lot of the bases you’re
likely to come across fit into this category.
We know generally a salt is a
combination of cations and anions, and the chemical symbol for water is H2O. But does the cation or anion come
from the acid or the base? Well, if we start with the base, we
know in this case it has to have OH− ions, which means it must be paired with a
cation. And the acid containing H+ ions
contributes the anion. So here we have the general
formation of a salt from an acid and a base, and H2O, water, is formed by the
reaction of H+ and OH− ions.
Let’s start with some of the acids
you might be familiar with and see which anions they contribute to a salt. Hydrochloric acid, HCL, will react
with many different bases. Whatever the base is, the reaction
will always produce a chloride salt, a salt that contains chloride ions, Cl−. Sulfuric acid, H2SO4, will
generally react with bases to produce sulfate salts, salts containing SO42−
ions. Nitric acid, HNO3, will produce
nitrate salts, salts containing NO3− ions. And hydrobromic acid will react
like hydrochloric acid, but instead producing bromide salts. So we should be able to apply this
to any acid.
Now let’s have a look at a few
example bases. Sodium hydroxide, a common base,
has the formula NaOH. When sodium hydroxide reacts with
an acid, it produces a sodium salt containing the Na+ cation. When potassium hydroxide, KOH,
reacts with acids, we produce potassium salts containing K+ ions. And we see a similar behavior for
ammonium hydroxide, NH4OH. Ammonium hydroxide reacts with acid
to produce the ammonium ion, NH4+, and ammonium salts. The majority of salts are metal
salts because they are derived from metallic elements. But there are nonmetal salts, like
ammonium salts, which are derived from nonmetals.
Now let’s put these two components
together and see which salts we can make. Acid plus base react to form salt
plus water. If we react together hydrochloric
acid and sodium hydroxide, the salt formed will be made up of anions from the
hydrochloric acid, meaning we’re getting chloride anions. And our cations Na+ or sodium ions
come from the base, sodium hydroxide. We can write the formula HCl plus
NaOH react to form NaCl plus H2O. So what about some other acids and
bases? What do we get if we react sulfuric
acid and potassium hydroxide? The acid contributes the sulfate
anion, and the base contributes the potassium cation, giving us potassium
sulfate. We can convert the word equation to
the symbol equation. And since sulfuric acid is
diprotic, it has two hydrogen ions rather than one, we need 2KOH in order to
balance, producing one K2SO4 plus 2H2O.
Next, we have nitric acid and
magnesium hydroxide, which react to produce magnesium nitrate. And here are the chemical
formulas. Look out for magnesium which has a
charge of two plus, meaning we have two OH− ions. This means we need twice as much
nitric acid as we have magnesium hydroxide in order to balance the equation. You could even take a good guess at
what would happen if you took phosphoric acid and ammonium hydroxide. Phosphoric acid produces the
phosphate anion. So we get ammonium phosphate. This one’s a little bit more
tricky, so I’m just going to give you the balanced equation and move on.
From the last section, we saw a lot
of names of salts. How would we go about naming a salt
that we’ve never heard of? This is the formula of a salt,
HgS. Hg is a symbol for the element
mercury, and S is the symbol for the element sulfur. Mercury is a metallic element, and
sulfur is a nonmetallic element. We can remember this from the
position of these elements on the periodic table. To the left of this zigzag line, we
tend to find metals, and to the right, we find nonmetals. Therefore, we expect HgS to be an
ionic compound. Metals tend to lose electrons more
easily than nonmetals, so we’d expect the metal, mercury, to contribute the cations
and the nonmetal, sulfur, to contribute the anions.
Sulfur like oxygen is in group 16,
otherwise known as group six, of the periodic table. We would therefore anticipate that
atoms of sulfur would gain two electrons each to form S2− ions. Since in the formula, mercury and
sulphur are in a ratio of one to one, we must have Hg2+ ions as well. When we name ionic compounds like
salts, we always put the name of the cation first and then the name of the
anion.
The name of a metal cation is the
same as the name of the metal, so mercury to mercury. But the name of the anion is
different. In this case, we have sulfur
transforming into sulfide. -ide indicates we’re dealing with
an anion that’s monatomic, a single nucleus. And for reference, the suffix -ate
or A-T-E has a slightly more complicated meaning. But it always means we’re dealing
with a polyatomic anion containing oxygen and one other element. In this case, however, our final
name is mercury sulfide. Mercury, however, does display
multiple oxidation states sometimes, so we could be extra precise and write the name
of mercury sulfide as mercury(II) sulfide.
However, for elements in the main
group, we generally won’t need to do this. We can easily tell the name of a
salt from other chemical names in these ways. There will always be at least two
distinct terms, one for the cation and one for the anion. They also, generally speaking,
won’t use prefixes like mono-, di-, and tri-. So, for instance, magnesium
chloride, MgCl2, would not be called magnesium dichloride. But you will see at the end of the
name for the anion suffixes like -id, -ate, and -ite. -ate and -ite both describe
different polyatomic anions containing an element and some oxygen. But we don’t need to go into the
distinctions in this video.
So we’ve looked at breaking down
salts into metallic and nonmetallic salts. But there’s another property which
is solubility that’s often used to categorize salts. You might hear about a salt being
either soluble or insoluble. But this is a rough grouping, and
solubility is a continuous spectrum, going from completely insoluble all the way to
completely soluble, which is what we call miscible. Two miscible substances will form a
solution no matter what ratio they are in. One of the most common ways we
assess solubility is by seeing how much mass we can dissolve in a given volume of
liquid.
In this case, we’re looking at the
number of grams of substance we can dissolve in 100 ml of pure water. We call the solution with as much
substances we can ordinarily dissolve a saturated solution. Because of the range of
solubilities in these examples, I’m going to have to use a log scale, where each
increment indicates multiplying or dividing by 10. Our favorite salt, sodium chloride,
comes in at about 36 grams per 100 milliliters at 20 degrees Celsius. And similar metal chlorides come in
with similar solubilities, with magnesium chloride and aluminum chloride being a
little higher. And toward the other end of the
spectrum, we have a substance we generally consider insoluble, which is calcium
carbonate. Depending on the form, it has a
solubility around seven times 10 to the negative four grams per 100 ml of water.
However, there are substances even
less soluble than this. On this metric, silver iodide is
about 40,000 times less soluble than calcium carbonate. Silver bromide isn’t much better,
and even silver chloride doesn’t make it over the hill. But comparatively speaking, silver
fluoride is incredibly soluble at 172 grams per 100 milliliters.
So all we can be sure of is that as
we move to the right, the substances are more soluble, and as we move to the left,
they are more insoluble. But what tends to happen is that
anything below a certain threshold is just called insoluble, and anything above is
just called soluble. The position of the boundary
doesn’t need to be actually clear, because there’s such a big difference between the
common salts we call soluble and the common salts we call insoluble. So for the next bit, just bear in
mind the rough difference between insoluble and soluble.
What we are going to look at next
is how to synthesize some of these salts practically. If a salt is insoluble or poorly
soluble, we can sometimes synthesize it using a precipitation reaction. A precipitation reaction is simply
a reaction when a solid is produced from a solution. In a precipitation reaction, we
typically see one or more dissolved solutes, reactants, produce at least one solid
product. In the lab, you’ll typically see
these performed by the mixing of two different aqueous solutions. Chemicals in the two solutions will
react and form a very fine powder of solid product.
These particles will either stick
around, floating around in solution, forming what we call a suspension. Or the particles will quickly clump
together and fall to the bottom of the container, forming a precipitate. For some suspensions, it may just
take a great deal of time in order for the solid to collect at the bottom. Whether the solid collects or not,
the next step is the same. The mixture is stirred up and the
whole collection is filtered, leaving the solid in the filter paper, which can be
washed with more solvent, dried, and left pure.
We can demonstrate this whole
process using lead nitrate and potassium iodide solutions. Both of these solutions are
colorless. When the two solutions mix,
potassium iodide quickly forms. It’s an insoluble, shiny, yellow
solid. These characteristics give the
general experiment its name, the golden rain experiment. After filtration, washing, and
drying, we end up with pure lead iodide. But filtration on its own will not
work if the salt is soluble. If the salt is soluble, it won’t be
easy to separate from the rest of the solution, which will have potentially other
products and leftover reactants.
The first scenario is when we are
making a salt from an acid and a base, and the acid and the base are both
soluble. If we’re dealing with our simple
acids and bases, we’re going to produce salt and water, which is fine. But we really don’t want any of the
acid or base left over at the end. The easiest way to guarantee at
least a relatively pure product is to use exactly the right amount of acid and
base. Let’s have a look at a scenario
where we’re making barium chloride, the salt, from hydrochloric acid and barium
hydroxide. And this is what we get when we
convert the names into the chemical formulas. But we need to balance by adding
2HCl per Ba(OH)2.
So let’s imagine we’re mixing
together one-molar solutions at each reactant. In order to get twice as much HCl
reacting with barium hydroxide, we’d need to have double the volume of our one-molar
HCl solution. So we’d mix the solutions in a
ratio of two to one. This would get us our final
solution of barium chloride in a relatively pure form. And then we could remove the
solvent, the water, by evaporating it off in an evaporation dish. If at the beginning we’d measured
exactly the right amounts of hydrochloric acid and barium hydroxide, we’d end up
with pure barium chloride.
Now, the last scenario we’re going
to look at is when we synthesize a soluble salt using a soluble acid and an
insoluble base. Since we can remove solids easily
by filtration, all we need to do to get a pure product is add an excess of the solid
base, so we use up all the acid. We’d add the solid base to the acid
solution, make sure we had an excess and that all the acid was reacting, giving it a
good stir just to make sure. This would give us our pure salt
solution with some base we just need to filter off. At the end of filtration, we’d have
our pure solution in a flask. And after evaporation, we’d have
our pure dry salt.
Now, before we finish, there’s one
more topic about salts we need to address. And that is that salts themselves
can be acidic, neutral, or basic. Acidic salts produce acidic
solutions and react with bases. Basic salts produce basic solutions
and react with acids. Neutral salts produce neutral
solutions and don’t react either with acids or bases. So neutral salts produce solutions
with pH about seven. Acidic salts produce solutions with
pH less than seven. And basic salts produce solutions
with pH greater than seven.
One of the most well-known acidic
cations is ammonium, NH4. But most cations and salts are
neutral, particularly the metal salts. Basic anions include carbonate,
CO32−, and hydrogen carbonate, HCO3−, fluoride, F−. And you can even consider oxide
ions basic because oxides tend to react with acids. The group of neutral anions
includes the other halides — chloride, bromide, and iodide; nitrate, NO3−; and
sulfate, SO42−, although there are arguments to be made that SO42− is slightly
basic.
When we do an acid base reaction
that produces a salt, we can look at the strength of the acid or base to see what
type of salt we’re likely to produce. A strong acid and a strong base
will produce a neutral salt. A strong acid and a weak base will
produce an acidic salt. A weak acid and a strong base will
produce a basic salt. And a weak acid and weak base will
produce generally a neutral salt, although it can depend.
So to sum up, the salt is made of
cations and anions and can be made by an acid–base reaction. The acid provides the anion and the
base provides the cation. Salts are made in different ways,
depending on their water solubility and the solubility of the acid and base. Salts can be acidic, neutral, or
basic. Strong acids react to produce
neutral anions, and weak acids react to produce basic anions. And strong bases produce neutral
cations and weak bases produce acidic cations.