Question Video: Determining the Number of Orbitals in a Shell Given the Principal Quantum Number | Nagwa Question Video: Determining the Number of Orbitals in a Shell Given the Principal Quantum Number | Nagwa

Question Video: Determining the Number of Orbitals in a Shell Given the Principal Quantum Number Chemistry • Second Year of Secondary School

What is the number of orbitals in the shell that has the principal quantum number 𝑛 = 1?

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Video Transcript

What is the number of orbitals in the shell that has the principal quantum number 𝑛 equals one?

Inside of an atom, electrons are found in various energy levels called shells. The principal quantum number 𝑛 represents the shell where the electron is found. 𝑛 can be any positive integer. As 𝑛 increases, the electron will be at a higher energy and less tightly bound to the nucleus.

Shells consist of one or more subshells. Subshells are described by the subsidiary quantum number 𝑙. The number of subshells within a shell depends on the principal quantum number. For a given value of 𝑛, 𝑙 can be any integer from zero to 𝑛 minus one. Each subsidiary quantum number corresponds to a different type of subshell, with s, p, d, and f being the most common that we’ll encounter.

Each subshell is composed of one or more different orbitals. The orientation of these orbitals can be described using the magnetic quantum number 𝑚 subscript 𝑙. The number of orbitals in a subshell depends on the subsidiary quantum number. For a given value of 𝑙, 𝑚 subscript 𝑙 can be any integer from negative 𝑙 to positive 𝑙.

With all of this information in mind, let’s return to the question. We are told in the question that a shell has the principal quantum number of one. The subsidiary quantum number can be any integer from zero to 𝑛 minus one. So zero is the only possible value for the subsidiary quantum number when 𝑛 equals one. So this shell only contains one subshell, the s-type subshell. The magnetic quantum number can be any integer from negative 𝑙 to positive 𝑙. So, when 𝑙 equals zero, 𝑚 subscript 𝑙 can only equal zero. The single magnetic quantum number indicates that this subshell only contains one orbital. This lone orbital is an s orbital, which is spherical in shape.

From this, we can see that a shell with the principal quantum number of one contains a single subshell that contains a single orbital. So the number of orbitals in the shell that has the principal quantum number 𝑛 equals one is one.

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